肖庭庭,李征涛,董浩,陈坤,于文远,王一恒
XIAO Ting-ting,LI Zheng-tao,DONG Hao,CHEN Kun,YU Wen-yuan,WANG Yi-heng

• 1:上海理工大学
• 2:上海天祥质量技术服务有限公司

摘要(Abstract)：

作为一种兼顾环保、节能的制冷剂,R290与R22的标准沸点、凝固点、临界点等基本物理性质非常接近,具备替代R22的基本条件,拥有广阔的应用前景和市场价值。但由于其与空气混合能形成易燃易爆混合物,存在重大安全隐患,抑制了R290制冷产品的推广和应用。本文通过总结国内外学者对改善R290制冷系统所做的研究,分析了R290替代R22存在的弊端,对提高R290系统安全性的解决方案进行综述,并根据最新研究,分别从减少制冷剂灌注量、间接使用R290以及加入阻燃剂方面对今后的研究方向作出展望,以期推广R290在制冷产品中的使用。
As a both environmental protection and energy saving refrigerant,R290,with the basic conditions to substitute for R22 due to its very close to the basic physical properties such as normal boiling point,freezing point and critical point,has wide application prospects and market value. The promotion and application of R290 refrigeration products are suppressed because of significant security risks from the explosive mixtures formed with R290 and air. This paper analyzed the disadvantages of using R290 to substitute for R22 and summarized security solutions of R290 system through the review of both domestic and international investigations on improvement of R290 refrigeration system. Besides,the development and trend of R290 is also proposed based on the latest research progresses in the aspects of reducing refrigerant charge,indirect using R290 as well as adding flame retardants,respectively,with the aim at promoting the use of R290 in refrigeration products.

关键词(KeyWords)： R290;安全性;灌注量减少;间接使用;阻燃剂;综述及展望
R290;security;charge reduction;indirect using;flame retardants;overview and prospect

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 肖庭庭,李征涛,董浩,陈坤,于文远,王一恒
XIAO Ting-ting,LI Zheng-tao,DONG Hao,CHEN Kun,YU Wen-yuan,WANG Yi-heng

参考文献(References)：

• [1]马一太,王伟.制冷剂的替代与延续技术[J].制冷学报,2010,31(5):11-17.
• [2]刘荣,陶乐仁,高立博,等.R410A在内螺纹管内无润滑油沸腾换热实验研究[J].制冷学报,2011,32(4):20-24.
• [3]史琳,朱明善.家用/商用空调用R32替代R22的再分析[J].制冷学报,2010,31(1):1-5.
• [4]李连生.制冷剂的替代技术研究进展及发展趋势[J].制冷学报,2011,32(6):53-58.
• [5]宁静红,刘圣春,彭苗,等.R290制冷空调系统的现状与未来发展[J].流体机械,2012,40(7):72-79.
• [6]常琳,祝伟.制冷剂R290的国内研究进展[J].制冷与空调,2011,11(3):65-68.
• [7]肖洪海,张桃,胡艳.R290小型家用空调器的性能匹配研究[J].制冷学报,2006,27(4):26-30.
• [8]杨林德,吴建华,候杰.分体式房间空调器R290和R1270替代R22实验研究[J].制冷学报,2013,34(2):9-14.
• [9]李廷勋,杨久铭,曾昭顺,等.R290灌注式替代R22空调整机性能研究[J].制冷学报,2010,31(4):31-34.
• [10]Teng T P,Mo H E,Lin H,et al.Retrofit Assessment of Window Air Conditioner[J].Applied Thermal Engineering,2012,32(1):100-107.
• [11]Zhou Guobing,Zhang Yufeng.Performance of a splittype air conditioner matched with coiled adiabatic capillary tubes using HCFC22 and HC290[J].Applied Energy,2010,87(5):1522-1528.
• [12]International Electrotechnical Commission.IEC 60335-2-40:2005.Household and similar electrical appliances-Safety-part 2-40:Particular requirements for electrical heat pumps,air-conditioners and dehumidifiers[S].Geneva:IEC,2005.
• [13]British Standards Institution.BS EN 378-1:2008.Refrigerating systems and heat pumps-Safety and environmental requirements-Part 1:Basic requirements,definitions,classification and selection criteria[S].London:BSI,2008.
• [14]Corberán J M,Martínez I O,Gonzálvez J.Charge optimisation study of a reversible water-to-water propane heat pump[J].International Journal of Refrigeration,2008,31(4):716-726.
• [15]贾庆贤,赵夫峰,曾昭顺,等.4mm管换热器降低制冷剂充注量实验研究[J].制冷技术,2010,30(2):26-27.
• [16]王婷婷,任滔,丁国良,等.小管径空调器的优化设计[J].制冷技术,2012,32(4):1-4.
• [17]高晶丹,丁国良,王婷婷,等.R290空调器的优化设计原则[J].制冷技术,2013,33(1):23-26.
• [18]刘振,赖想球,周向阳,等.R290家用空调制热特性研究[J].流体机械,2013,41(3):82-84.
• [19]高晶丹,吴伟,丁国良,等.空调器用小管径翅片管蒸发器的优化设计方法[J].化工学报,2012,63(S2):42-48.
• [20]Hrnjak P,Litch A D.Microchannel heat exchangers for charge minimization in air-cooled ammonia condensers and chillers[J].International Journal of Refrigeration,2008,31(4):658-668.
• [21]Park C Y,Hrnjak P.Experimental and numerical study on microchannel and round-tube condensers in a R410A residential air-conditioning system[J].International Journal of Refrigeration,2008,31(5):822-831.
• [22]谭易君,庄嵘,涂小苹,等.R290微通道冷凝器性能优化及其充注量分析[J].制冷与空调,2013,13(3):97-100+104.
• [23]李峰,徐博,杨涛,等.家用空调微通道换热器流量分配特性研究[J].制冷技术,2012,32(3):13-17.
• [24]Cavallini A,Riva E D,Col D D.Performance of a large capacity propane heat pump with low charge heat exchangers[J].International Journal of Refrigeration,2010,33(2):242-250.
• [25]Shao L L,Yang L,Zhang C L,et al.Numerical modeling of serpentine microchannel condensers[J].International Journal of Refrigeration,2009,32(6):1162-1172.
• [26]何国庚,刘漩斐.R290在小型空调器中替代R22的优势与问题及其解决措施[J].制冷与空调,2008,8(2):58-62.
• [27]肖友元,刘畅,郭春辉,等.自然工质R290在家用空调器中的应用研究[J].流体机械,2009,37(5):61-65.
• [28]杨瑞杰,杨忠学,孙蓉,等.自然制冷剂R290与冷冻机油的相溶性研究[J].制冷学报,2013,34(5):23-27.
• [29]毛水林,王建敏,王秋菊,等.烷基苯冷冻机油在R290压缩机中的试验研究[J].电器,2013,(S1):614-618.
• [30]Fernando P,Palm B,Lundqvist P,et al.Propane heat pump with low refrigerant charge:design and laboratory tests[J].International Journal of Refrigeration,2004,27(7):761-773.
• [31]Martínez-Galván I,Gonzálvez-MaciáJ,Corberán J M,et al.Oil type influence on the optimal charge and performance of a propane chiller[J].International Journal of Refrigeration,2011,34(4):1000-1007.
• [32]黄玉优,尹茜,于静,等.R290空气源热泵热水器的试验研究与对比[J].制冷与空调,2011,11(3):57-60.
• [33]李静,陈剑波,岳畏畏,等.R290在热泵空调热水器中的应用实验研究[J].能源研究与信息,2011,27(3):174-180.
• [34]张永梨,童明伟,童庆明.大型螺杆式冷水机组使用绿色环保工质的实验研究[J].制冷学报,2002,23(1):32-35.
• [35]童明伟,吴治娟,董茂林.R290的可燃爆炸性试验及在制冷机组中的试用[J].重庆大学学报(自然科学版),2002,25(1):36-39.
• [36]郭春辉,刘知新,徐永恩,等.R290空调器系统混空气实验研究[J].制冷与空调,2013,13(5):58-61.
• [37]刘知新,郭春辉,刘畅,等.R290家用空调器安全性实验研究[J].制冷技术,2011,31(1):22-26.
• [38]徐明仿,杜维明,晏刚.可燃制冷剂抑爆方法[J].家电科技,2004,(2-3):106-109.
• [39]唐汝宁,宋智.丙烷与R22混合工质可燃性分析及相关实验方法研究[J].内蒙古工业大学学报(自然科学版),2000,19(4):289-293.
• [40]张于峰,马九贤,孙延禄,等.丙烷及其混合物作为空调制冷剂可行性研究[J].制冷学报,1999,20(2):18-24.
• [41]楚银盾,金听祥,张卫士.R290在房间空调器中的研究现状[J].制冷技术,2013,33(3):70-76.
• [42]田贯三,马一太,杨昭,等.可燃制冷剂爆炸极限及抑制的理论与实验研究[J].山东建筑工程学院学报,2001,16(2):58-63.
• [43]徐明仿,杜维明,晏刚.近共沸制冷剂R134a/R290的研究[J].制冷与空调,2004,4(5):71-74.
• [44]钱伟,王维,钱文波,等.替代制冷剂R134a/R290与润滑油的互溶性实验研究关[J].制冷与空调,2008,8(3):31-35.
• [45]Jung D,Song Y,Park B.Performance des mélanges de frigorigènes utilisés pour remplacer le HCFC22[J].International Journal of Refrigeration,2000,23(6):466-474.
• [46]孙尔雁,李振明,公茂琼,等.全卤代烃CF3I和CF4的阻燃能力实验[J].低温工程,2011,(2):13-18.
• [47]王怀信,刘方,马利敏.空调循环中HCs/阻燃剂混合工质的泄漏特性[J].工程热物理学报,2004,25(1):17-20.
• [48]王怀信,李海龙,马利敏.碳氢化合物/阻燃剂混合工质替代HCFC22的研究[J].工程热物理学报,2003,24(1):13-15.
• [49]王怀信,张宇,郑臣明,等.三氟碘甲烷作为冰箱制冷剂的理论循环分析[J].制冷学报,2005,26(1):33-37.
• [50]冯永斌,晏刚,钱文波.新型混合制冷剂R1270/R152a/R13I1的理论研究[J].制冷学报,2010,31(1):27-30.
• [51]宁静红,李惠宇,彭苗.R290/CO2复叠式制冷系统的性能实验[J].制冷学报,2007,28(6):57-60.
• [52]牛宝联,张于峰.CO2/R290应用于复叠制冷低温环路浓度配比实验研究[J].制冷学报,2010,31(1):35-38.
• [53]宁静红,马一太,李敏霞.R290/CO2自然工质低温复叠式制冷循环理论分析[J].天津大学学报,2006,39(4):449-453.
• [54]齐洪洋,高磊,张莹莹,等.管壳式换热器强化传热技术概述[J].压力容器,2012,29(7):77-82.
• [55]裴坤,孔晓玲,殷凤江,等.太阳能蒸汽热风干燥技术的研究[J].包装与食品机械,2012,30(2):15-18.
• [56]Nicola G D,Polonara F,Stryjek R,et al.Performance of cascade cycles working with blends of CO2+natural refrigerants[J].International Journal of Refrigeration,2011,34(6):1436-1445.